1,1′-Bis(diphenylphosphino)ferrocene CAS 12150-46-8 DPPF Purity >98.0% Fe 9.7~10.4%
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| Chemical Name | 1,1'-Bis(diphenylphosphino)ferrocene |
| Synonyms | 1,1'-Ferrocenebis(diphenylphosphine); DPPF |
| CAS Number | 12150-46-8 |
| CAT Number | RF-PI2275 |
| Stock Status | In Stock, Production Scale Up to Tons |
| Molecular Formula | C34H28FeP2 |
| Molecular Weight | 554.39 |
| Sensitive | Air Sensitive |
| Solubility in Water | Insoluble in Water |
| Solubility | Soluble in Chloroform |
| Hydrolytic Sensitivity | 7: Reacts Slowly With Moisture/Water |
| Brand | Ruifu Chemical |
| Item | Specifications |
| Appearance | Yellow to Orange Powder |
| Purity / Analysis Method | >98.0% (Chelometric Titration) |
| Iron (Fe) | 9.7~10.4% (Titration by Na2S2O3) |
| Carbon by Elemental Analysis | 71.1~76.2% |
| Melting Point | 181.0~183.0℃ |
| Water by Karl Fischer | <0.50% |
| Solubility in CHCL3 | Yellow to Orange, Clear(2.5%) Pass |
| Infrared Spectrum | Conforms to Structure |
| Test Standard | Enterprise Standard |
Package: Bottle, Aluminium foil bag, 25kg/Cardboard Drum, or according to customer's requirement
Storage Condition: Store in sealed containers at cool and dry place; Protect from light and moisture
1,1'-Bis(diphenylphosphino)ferrocene (CAS: 12150-46-8), Suzuki-Miyaura Cross Coupling Reaction, Ligands, Organic Metallic Catalysts. Generally used in the following chemical reactions namely Buchwald-Hartwig Cross Coupling Reaction, Carbonylations, Ene Reaction, Heck Reaction, Negishi Coupling, Sonogashira Coupling, Stille Coupling, Suzuki-Miyaura Coupling, Tsuji-Trost Reaction. Applications Commonly used coordination compound in synthesis, readily forms complexes with various metals, i.e. when reacting with the acetonitrile or benzonitrile complexes of PdCl2 it forms (dppf)PdCl2, which is a popular reagent for palladium-catalyzed coupling reactions. Novel functionalized furan derivatives were prepared via Pd-phosphine sequential C-C and C-O bond formation. Ligand used in a Pd(II)-catalyzed cross-coupling synthesis of oxazepine ring systems. 1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.
