[Ir(cod)Cl]2 CAS 12112-67-3 Chloro(1,5-Cyclooctadiene)iridium(I) Dimer Purity ≥98.0% (HPLC) Ir ≥57.0%

Short Description:

Chloro(1,5-Cyclooctadiene)iridium(I) Dimer

Synonyms: [Ir(cod)Cl]2

Bis(1,5-Cyclooctadiene)diiridium(I) Dichloride

CAS: 12112-67-3

Purity: ≥98.0% (Argentometric Titration)

Iridium (Ir) Content: ≥57.0%

Appearance: Red to Orange Powder

Contact: Dr. Alvin Huang

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E-Mail: alvin@ruifuchem.com

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Product Detail

Product Tags

Description:

Ruifu Chemical is the leading manufacturer of Chloro(1,5-Cyclooctadiene)iridium(I) Dimer ([Ir(cod)Cl]2) (CAS: 12112-67-3) with high quality. Ruifu Chemical can provide worldwide delivery, competitive price, excellent service, small and bulk quantities available. Purchase [Ir(cod)Cl]2, Please contact: alvin@ruifuchem.com

Chemical Properties:

Chemical Name	Chloro(1,5-Cyclooctadiene)iridium(I) Dimer
Synonyms	[Ir(cod)Cl]2; [Ir(1,5-cod)Cl]2; Bis(1,5-Cyclooctadiene)diiridium(I) Dichloride; 1,5-Cyclooctadiene-iridium(I) Chloride Dimer; Di-μ-Chlorobis[(1,2,5,6-η)-1,5-Cyclooctadiene]diiridium; Iridium(I) Chloride 1,5-Cyclooctadiene Complex Dimer
Stock Status	In Stock, Commercial Production
CAS Number	12112-67-3
Molecular Formula	C16H24Cl2Ir2
Molecular Weight	671.70 g/mol
Melting Point	205℃(dec.)(lit.)
Sensitive	Air Sensitive, Heat Sensitive, Moisture Sensitive
Water Solubility	Insoluble in Water
Solubility	Soluble in Chloroform and Toluene. Slightly Soluble in Acetone and Alcohol
Hydrolytic Sensitivity	7: Reacts Slowly with Moisture/Water
COA & MSDS	Available
Origin	Shanghai, China
Category	Metal Catalysts
Brand	Ruifu Chemical

Specifications:

Items	Inspection Standards	Results
Appearance	Red to Orange Powder	Complies
Water by Karl Fischer	<0.50%	0.85%
Purity / Analysis Method	≥98.0% (Argentometric Titration)	98.53%
Iridium (Ir) Content	≥57.0%	57.2%
ICP	Confirms Iridium Component	Confirmed
Proton NMR Spectrum	Conforms to Structure	Complies
Conclusion	The product has been tested and complies with the given specifications

Package/Storage/Shipping:

Package: Glass Bottle, Fluorinated Bottle, Aluminium foil bag, or according to customer's requirement.
Storage: Keep the container tightly closed and store in a cool, dry (2~8℃) and well-ventilated warehouse away from incompatible substances. Protect from air, heat and moisture. Incompatible with strong oxidizing agents.
Shipping: Deliver to worldwide by air, by FedEx / DHL Express. Provide fast and reliable delivery.

Advantages:

Sufficient Capacity: Sufficient facilities and technicians

Professional Service: One stop purchasing service

OEM Package: Custom package and label available

Fast Delivery: If within stock, three days delivery guaranteed

Stable Supply: Maintain reasonable stock

Technical Support: Technology solution available

Custom Synthesis Service: Ranged from grams to kilos

High Quality: Established a complete quality assurance system

FAQ:

How to Purchase? Please contact Dr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com
15 Years Experience? We have more than 15 years of experience in the manufacture and export of a wide range of high quality pharmaceutical intermediates or fine chemicals.
Main Markets? Sell to domestic market, North America, Europe, India, Korea, Japanese, Australia, etc.
Advantages? Superior quality, affordable price, professional services and technical support, fast delivery.
Quality Assurance? Strict quality control system. Professional equipment for analysis include NMR, LC-MS, GC, HPLC, ICP-MS, UV, IR, OR, K.F, ROI, LOD, MP, Clarity, Solubility, Microbial limit test, etc.
Samples? Most products provide free samples for quality evaluation, shipping cost should be paid by customers.
Factory Audit? Factory audit welcome. Please make an appointment in advance.
MOQ? No MOQ. Small order is acceptable.
Delivery Time? If within stock, three days delivery guaranteed.
Transportation? By Express (FedEx, DHL), by Air, by Sea.
Documents? After sales service: COA, MOA, ROS, MSDS, etc. can be provided.
Custom Synthesis? Can provide custom synthesis services to best fit your research needs.
Payment Terms? Proforma invoice will be sent first after confirmation of order, enclosed our bank information. Payment by T/T (Telex Transfer), PayPal, Western Union, etc.

12112-67-3 - Risk and Safety:

Hazard Symbols Xi - Irritant
Risk Codes
36/37/38 - Irritating to eyes, respiratory system and skin.
Safety Description
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39 - Wear suitable gloves and eye/face protection
WGK Germany 3
FLUKA BRAND F CODES 10
TSCA No
HS Code 2843 9000.99

12112-67-3 - Uses:

Chloro(1,5-Cyclooctadiene)iridium(I) Dimer ([Ir(cod)Cl]2) (CAS: 12112-67-3) is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.

Chloro(1,5-Cyclooctadiene)iridium(I) Dimer is an organic precious metal catalyst, used for the asymmetric hydrogenation reaction of non-functionalized outer ring double carbon bonds catalyzed by iridium.

12112-67-3 - Reactions:

Can be used to catalyse hydrosilylation and hydrogenation reactions
Precursor for Photocatalyst Synthesis
A metal precursor for asymmetric allylic substitutions
Pre-catalysts for asymmetry and cross-coupling catalysis reactions
Synthesis of precious metal iridium catalyst precursor
C-H Bond Activation Reaction
Transition Metal Catalysts
Easily-preparable N-Heterocyclic Carbene (NHC) Precursors
Precursor to catalysts for the asymmetric hydrogenation of tri- and tetrasubstituted olefins.
Precursor to catalyst for enantioselective reduction of imines.
Precursor to catalyst for allylic alkylation.
Precursor to catalyst for allylic amination and etherification.
Precursor to catalyst for the reaction of aroyl chlorides with internal alkynes to produce substituted naphthalenes and anthracenes.
Ir-catalyzed addition of acid chlorides to terminal alkynes.
Intramolecular hydroamination of unactivated alkenes with secondary alkyl- and arylamines.
Enantioselective [2+2] cycloaddition.
Silyl-directed, Ir-catalyzed ortho-borylation of arenes.
Ir-catalyzed cross-coupling of styrene derivatives with allylic carbonates.
Transfer hydrogenative C-C coupling